EACR25-1342
CPL410005 is a potent UBA1 inhibitor with strong anti-cancer activity in vitro. However, its systemic toxicity and poor tumor selectivity limit its therapeutic potential as a standalone small-molecule drug. To overcome these limitations, this study explores the conjugation of CPL410005 to an anti-HER2 antibody to enhance tumor specificity and reduce off-target effects. Targeting the Ubiquitin-Proteasome System (UPS) with Antibody-Drug Conjugate (ADC) for directed UBA1 inhibition represents a promising strategy for cancer therapy.
CPL410005 cytotoxicity was assessed across a broad panel of cancer cell lines. Its pharmacokinetic properties, including solubility, metabolic stability, and hepatotoxicity, were evaluated in vitro. To improve tumor-specific targeting, CPL410005 was conjugated to an anti-HER2 antibody via a selectively cleavable linker. ADCs were characterized in vitro for stability, HER2 binding affinity (SPR), and cytotoxic effects in HER2-positive and HER2-negative cell lines.
CPL410005 exhibited potent in vitro cytotoxicity on a panel of 130 cell lines, with IC50 values of 15.3 nM in U937 and 22.7 nM in HCT116 cell lines. However, systemic administration in xenograft models resulted in dose-limiting toxicity at 10 mg/kg. ADC conjugation significantly improved tumor-specific uptake, with conjugation yields above 85%, as confirmed by RP-HPLC. HER2-ADC conjugates retained high HER2 binding affinity (KD = 1.2 nM) and displayed selective cytotoxicity in HER2-overexpressing SK-OV-3 and SK-BR-3 cells, with IC50 values of 1.8 nM and 2.5 nM, respectively. No significant cytotoxicity was observed in HER2-negative HEK293 cells at concentrations up to 1 µM. Pharmacokinetic studies showed prolonged plasma half-life (t1/2 = 18.2 h) compared to free CPL410005 (t1/2 = 2.9 h), while linker cleavage-dependent drug release ensured selective cytotoxicity in target cells.
CPL410005’s potent UBA1 inhibition utilized in the form of ADC technology enhances tumor selectivity and reduces systemic toxicity. These findings support further preclinical development of HER2-targeted UBA1 inhibitors as a novel therapeutic strategy for HER2-positive cancers. Project co-financed by NCBR, POIR.01.02.00-00-0009/17